J. Phys. IV France 114 (2004) 445
Supramolecular systems derived from pyrrolo-tetrathiafulvalene building blocksJ. Becher1, 1, K. Nielsen1 and J.O. Jeppesen1
1 Department of Chemistry, University of Southern Denmark (Odense University) Campusvej 55, 5230 Odense M, Denmark
The new pyrrolo[3,4-d]-TTF building blocks offers considerable scope as versatile building blocks for applications in macrocyclic, molecular, and supramolecular chemistry. Exemplified here by a receptor, such as the TTF-calixpyrrole. The starting 2,5-unsubstituted pyrrolo-TTF can also be used for preparation of tetra- or mono TTF-annelated porphyrins. Key words. Tetrathiafulvalene - TTF - supramolecular systems - host guest interactions - anion complexation - pyrrolo[3,4-]tetrathiafulvalene - calixpyrrole - tetrathiafulvalene annelated porphyrins.
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