J. Phys. IV France
Volume 114, April 2004
Page(s) 445 - 448

J. Phys. IV France
114 (2004) 445
DOI: 10.1051/jp4:2004114104

Supramolecular systems derived from pyrrolo-tetrathiafulvalene building blocks

J. Becher1, 1, K. Nielsen1 and J.O. Jeppesen1

1  Department of Chemistry, University of Southern Denmark (Odense University) Campusvej 55, 5230 Odense M, Denmark

The new pyrrolo[3,4-d]-TTF building blocks offers considerable scope as versatile building blocks for applications in macrocyclic, molecular, and supramolecular chemistry. Exemplified here by a receptor, such as the TTF-calix[4]pyrrole. The starting 2,5-unsubstituted pyrrolo-TTF can also be used for preparation of tetra- or mono TTF-annelated porphyrins. Key words. Tetrathiafulvalene - TTF - supramolecular systems - host guest interactions - anion complexation - pyrrolo[3,4-]tetrathiafulvalene - calix[4]pyrrole - tetrathiafulvalene annelated porphyrins.

© EDP Sciences 2004