Numéro |
J. Phys. IV France
Volume 123, March 2005
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Page(s) | 351 - 354 | |
DOI | https://doi.org/10.1051/jp4:2005123064 |
J. Phys. IV France 123 (2005) 351-354
DOI: 10.1051/jp4:2005123064
Study of the chemical mechanisms of the reaction of neutralization of calcium hydroxide by phosphoric acid
M. Elgadi, E. Mejdoubi, L.L. Elansari, A. Essaddek, S. Abouricha and A. LamhamdiLaboratoire de Chimie du Solide Minéral, Département de Chimie, Faculté des Sciences Université Mohamed I, Oujda, Maroc
Abstract
Calcium phosphates reported in this study, are prepared following
an acido-basic reaction between phosphoric acid and calcium hydroxide. These
phosphates are the brushite, tricalcium phosphate, hydroxyapatite and
oxygenated apatite. The follow-up of the reaction by infra-red spectroscopy
of absorption showed that the alkaline pH of calcium hydroxide solution,
favours the formation of carbonated apatite, at the start of the reaction.
Following the addition of phosphoric acid, the pH becomes increasingly
favourable to the formation of the desired phase. The insertion of molecular
oxygen in the apatitic tunnel is carried out by the use of hydrogen
peroxide. The molecular oxygen rate in the apatite is then determined by
volumetric analysis.
© EDP Sciences 2005