Numéro |
J. Phys. IV France
Volume 114, April 2004
|
|
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Page(s) | 557 - 559 | |
DOI | https://doi.org/10.1051/jp4:2004114132 |
J. Phys. IV France 114 (2004) 557
DOI: 10.1051/jp4:2004114132
Acetylenic scaffolding with derivatives of tetrathiafulvalene
M.B. Nielsen1, J.-P. Gisselbrecht2, S.B. Nielsen3, N. Thorup4, C. Boudon2 and M. Gross21 Department of Chemistry, University of Soutern Denmark, 5230 Odense M, Denmark
2 Laboratoire d'Électrochimie et de Chimie Physique du Corps Solide, UMR 7512, CNRS, Université Louis Pasteur, 67000 Strasbourg, France
3 Department of Physics and Astronomy, University of Aarhus, 8000 Aarhus C, Denmark
4 Department of Chemistry, Technical University of Denmark, 2800 Lyngby, Denmark
Abstract
A selection of tetrathiafulvalene (TTF) derivatives
containing acetylenic moieties have been synthesized and studied by cyclic
voltammetry and UV-Vis absorption spectroscopy. Ionization energy
calculations on some extended TTFs were carried out employing the DFT
method.
Key words. Alkynes -
-donors - tetrathiafulvalene.
© EDP Sciences 2004