| Numéro |
J. Phys. IV France
Volume 114, April 2004
|
|
|---|---|---|
| Page(s) | 459 - 462 | |
| DOI | https://doi.org/10.1051/jp4:2004114107 | |
J. Phys. IV France 114 (2004) 459
DOI: 10.1051/jp4:2004114107
Potentional photomagnetic materials based on cation photochromic mononitrosyl complex of ruthenium
L.A. Kushch1, L.S. Plotnikova1, Yu.N. Shvachko2, V.A. Emel'yanov3, E.B. Yagubskii1, 1, G.V. Shilov1 and S.M. Aldoshin11 Institute of Problems of Chemical Physics RAS, 142432 Chernogolovka, MD, Russia
2 Institute of Metal Physics Ural Division, RAS, GSP-170,620219 Ekaterinburg, Russia
3 Institute of Inorganic Chemistry, Siberian Division of RAS, 630090 Novosibirsk, Russia
Abstract
The synthesis of a series of novel compounds containing
the photochromic mononitrosyl cation [ Ru(NH
3)5NO]
3+ and metal
complex paramagnetic anions : [ Ru(NH
3)5NO] [ M(CN)
6] (M= Cr
(1), Fe (2)), [ Ru(NH
3)5NO] [ Cr(CN)
5NO] (3),
[ Ru(NH
3)5NO] [ M(ox)
3] (M=Cr (4), Fe (5)) is reported. The
crystal structure of salt 1 is discussed. The magnetic properties of 1 and 4
compounds studied by EPR and SQUID experimental techniques are presented.
Key words. Photochromism, X-ray analysis, Mononitrosyl complexes,
Hexacyanometallate, Magnetic properties.
© EDP Sciences 2004