Copper speciation in Iguaçu river basin, at Curitiba's metropolitan region, Brazil, by ligand competition using DPASV

Abstract
Copper concentrations and speciation in two different sites located in the Iguaçu River Basin, Brazil, were evaluated during a 10-months period, in this work. Results showed a seasonal influence on copper levels with a major contribution of non-point sources during the rainy season, when concentrations of copper were similar in both Irai and Iguaçu Rivers. During the dry season the discharge of raw sewage was the primary source of copper for the sampling point located downstream the city of Curitiba, in the Iguaçu River, which exhibited higher metal concentrations. Speciation results also showed different patterns. Higher copper contents were found in the particulate phase in Iguaçu River, whereas labile copper concentrations were relatively greater in Irai River waters.