| Numéro |
J. Phys. IV France
Volume 10, Numéro PR7, May 2000
International Workshop on Dynamics in Confinement
|
|
|---|---|---|
| Page(s) | Pr7-137 - Pr7-141 | |
| DOI | https://doi.org/10.1051/jp4:2000727 | |
International Workshop on Dynamics in Confinement
J. Phys. IV France 10 (2000) Pr7-137-Pr7-141
DOI: 10.1051/jp4:2000727
1 Institut für Experimentelle und Angewandte Physik, Universität Kiel, Olshausenstr. 40, 24098 Kiel, Germany
2 Institut für Physikalische Chemie, Universität Greifswald, Soldtmannstr. 23, 17487 Greifswald, Germany
3 Laboratoire Léon Brillouin, Centre d'Études de Saclay, 91191 Gif-sur-Yvette, France
© EDP Sciences 2000
J. Phys. IV France 10 (2000) Pr7-137-Pr7-141
DOI: 10.1051/jp4:2000727
Orientational ordering in methane condensates in mesoporous SiO2 modifications at low temperatures
B. Asmussen1, D. Balszunat1, C. Gutt1, W. Press1, W. Langel2, G. Coddens3 and R. Kahn31 Institut für Experimentelle und Angewandte Physik, Universität Kiel, Olshausenstr. 40, 24098 Kiel, Germany
2 Institut für Physikalische Chemie, Universität Greifswald, Soldtmannstr. 23, 17487 Greifswald, Germany
3 Laboratoire Léon Brillouin, Centre d'Études de Saclay, 91191 Gif-sur-Yvette, France
Abstract
The rotational spectra of CH4 at low temperatures have been used to investigate the disordering influence of a restricted geometry on the orientational structure of methane condensates in silicagels and Controlled Pore Glasses. A cross-over from complete orientational disorder to the partially ordered phase II of pure methane was observed with increasing pore diameter d at ≈ 120 Å.
© EDP Sciences 2000