| Numéro |
J. Phys. IV France
Volume 04, Numéro C9, Novembre 1994
Proceedings of the European Symposium on Frontiers in Science and Technology with Synchrotron Radiation
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| Page(s) | C9-397 - C9-400 | |
| DOI | https://doi.org/10.1051/jp4:1994966 | |
Proceedings of the European Symposium on Frontiers in Science and Technology with Synchrotron Radiation
J. Phys. IV France 04 (1994) C9-397-C9-400
DOI: 10.1051/jp4:1994966
1 Jozef Stefan Institute, Jamova 39, 61111 Ljubljana, and Department of Physics, University of Ljubljana, Slovenia
2 LURE, Université Paris-Sud, 91404 Orsay, France
© EDP Sciences 1994
J. Phys. IV France 04 (1994) C9-397-C9-400
DOI: 10.1051/jp4:1994966
Double photoexcitation [2(s,p)4(p,d)] in the Xe-isoelectronic series Cs+, Ba2+, La3+
A. Kodre1, I. Arcon1, M. Hribar1, M. Stuhec1, F. Villain2 and P. Parent21 Jozef Stefan Institute, Jamova 39, 61111 Ljubljana, and Department of Physics, University of Ljubljana, Slovenia
2 LURE, Université Paris-Sud, 91404 Orsay, France
Abstract
Using the standard ansatz, the single, strongly dissipated harmonic component of EXAFS in aqueous medium is eliminated from L-shell absorption spectra of Xe-like ions Cs+, Ba2+, La3+. The remaining structures in the spectra are interpreted as double photoexcitations into [2(s,p)4(p,d)] vacancy states : they are analogous to the corresponding structures in absorption spectra of xenon, their energies agree fully with MCDF energies. Their relative probabilities are found to increase along the isoelectronic series, proportionally to the intensity of the "white line" 2p→5d. For the first time, an "adiabatic" change of double excitation features is studied.
© EDP Sciences 1994