Numéro |
J. Phys. IV France
Volume 03, Numéro C1, Mai 1993
COMPLEX LIQUID SYSTEMS
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Page(s) | C1-163 - C1-169 | |
DOI | https://doi.org/10.1051/jp4:1993114 |
J. Phys. IV France 03 (1993) C1-163-C1-169
DOI: 10.1051/jp4:1993114
The physics of liquid water
J. TEIXEIRALaboratoire Léon Brillouin, CEA-CNRS, CE-Saclay, 91191 Gif-sur-Yvette cedex, France
Abstract
Liquid water is a particularly complex molecular liquid. This is due essentially to the intermolecular
hydrogen bond formation, the local tetrahedral symmetry and the short hydrogen bond lifetime. At
low temperatures, the geometric aspects of the hydrogen bond network are dominant. A
percolation approach of the spatial distribution of water molecules according to the number of their
hydrogen bonds leads to a qualitative explanation of most of the thermodynamic anomalies
observed at low temperature.
It is presented a short description of this percolation model and of its predictions of structural
and dynamic properties of liquid water. Some selected experimental results are presented and
intend to justify some of the hypothesis and main results of the theory.
© EDP Sciences 1993