Issue |
J. Phys. IV France
Volume 129, October 2005
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Page(s) | 15 - 19 | |
DOI | https://doi.org/10.1051/jp4:2005129004 |
J. Phys. IV France 129 (2005) 15-19
DOI: 10.1051/jp4:2005129004
Do intermolecular interactions reflect in sound velocity?
A. Burakowski and J. GlinskiFaculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland
Abstract
A new attempt in acoustical investigations of interactions between
components of liquid solution is presented and tested. It was shown, basing
on very simple assumptions and relatively simple experiment, that changes in
the concentration dependences of the adiabatic compressibility (calculated
from sound velocity and density data) are influenced by intermolecular
interactions occurring in solutions. However, it was also shown that these
changes are not very strong and the strongest are caused by processes, where
the total number of ions and/or their charge density are changing. We also
suggest that for some weak association-like processes the compressibility
can remain almost undisturbed and, consequently, not sensitive for them.
© EDP Sciences 2005