Issue |
J. Phys. IV France
Volume 117, October 2004
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Page(s) | 41 - 46 | |
DOI | https://doi.org/10.1051/jp4:2004117007 |
J. Phys. IV France 117 (2004) 41-46
DOI: 10.1051/jp4:2004117007
Spectroscopy in carbon deposits characterization
S. Pasieczna1, J. Ryczkowski1, T. Borowiecki1 and K. Stolecki21 University of Maria Curie-Sklodowska, 20-031 Lublin, Poland
2 Institute of Fertilizers, 24-110 Pulawy, Poland
Abstract
Carbon deposits formed on the top of the catalysts is characterized by a different morphology. This depends, among the others,
on the temperature of the catalytical reaction conducted. Application of FT-IR/PA (Fourier transform infrared photoacoustic)
spectroscopy allows to distinguish the carbon deposit forms created during the reaction. Deposits formed at high temperature
(steam reforming, hydrogenolysis) are graphite-like materials. In the contrary, at low temperature (hydrogenation of benzene)
deposits formed exhibit functional groups on its surface. Moreover, deposit created at low temperature has two parts: soluble
and insoluble.
© EDP Sciences 2004