Synthesis and magnetic studies of the ${\pi }$-d ferrimagnet TTF[ Cr(NCS)${_{4}}$(1,10$'$-phenanthroline)] , TTF = tetrathiafulvalene

S.S. Turner; S.G. Carling; P. Day; C.J. Gómez-Garcia; E. Coronado

doi:doi:10.1051/jp4:2004114139

Issue		J. Phys. IV France Volume 114, April 2004


Page(s)		585 - 587
DOI		https://doi.org/10.1051/jp4:2004114139

J. Phys. IV France 114 (2004) 585
DOI: 10.1051/jp4:2004114139

Synthesis and magnetic studies of the ${\pi }$ -d ferrimagnet TTF[ Cr(NCS) ₄(1,10 '-phenanthroline)] , TTF = tetrathiafulvalene

S.S. Turner^{1, 1}, S.G. Carling¹, P. Day¹, C.J. Gómez-Garcia¹ and E. Coronado¹

¹ Davy-Faraday Research Laboratory (DFRL), Royal Institution of Great Britain, 21 Albemarle Street, London, W1S 4BS, UK; Instituto de Ciencia Molecular (ICMol), Dpto. Quimica Inorganica, Univ. de Valencia, C/ Dr Moliner 50, 46100 Burjasot (Valencia), Spain

Abstract
A new synthesis route to the ${\pi }$ -d ferrimagnet TTF[ Cr(NCS) ₄(1,10 '-phenanthroline)] is described along with recent magnetic investigations. In particular the variable frequency AC magnetisation of the protonated and fully deuterated samples indicate no frequency dependence and a T $_{\rm c}$ of 8.7 K. Single crystal heat capacity and muon spin relaxation experiments show a second magnetic transition at 2.4 K. Key words. Charge-transfer salts, conductivity, ferrimagnetism.

Synthesis and magnetic studies of the -d ferrimagnet TTF[ Cr(NCS) 4(1,10 '-phenanthroline)] , TTF = tetrathiafulvalene

Synthesis and magnetic studies of the ${\pi }$ -d ferrimagnet TTF[ Cr(NCS) ₄(1,10 '-phenanthroline)] , TTF = tetrathiafulvalene