EDP Sciences logo
Subscriber Authentication Point
Search
Menu
Issue
J. Phys. IV France
Volume 114, April 2004
Page(s) 481 - 485
DOI https://doi.org/10.1051/jp4:2004114112


J. Phys. IV France 114 (2004) 481
DOI: 10.1051/jp4:2004114112

Exploitation of the photochromic nitroprusside anion [ FeNO(CN) 5] 2- as counterion for constructing molecular conductors: The first radical cation salts based on BDH-TTP and the amide functionalized derivatives of EDT-TTF

R. Shibaeva1, 1, S. Khasanov1, L. Zorina1, S. Simonov1, I. Shevyakova2, L. Kushch2, L. Buravov2, E. Yagubskii2, S. Baudron3, C. Mézière3, P. Batail3, E. Canadell4 and J. Yamada5

1  Institute of Solid State Physics, RAS, 142432 Chernogolovka MD, Russia
2  Institute of Problems of Chemical Physics, RAS, 142432 Chernogolovka MD, Russia
3  Chimie Inorganique, Matériaux et Interfaces, FRE 2447, CNRS-Université d'Angers, Bâtiment F, 2 boulevard Lavoisier, 49045 Angers, France
4  Institut de Ciència de Materials de Barcelona (CSIC), Campus de la UAB, 08193 Bellaterra, Spain
5  Department of Material Science, Faculty of Science, Himeji Institute of Technology, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan


Abstract
The radical cation salts based on BDH-TTP and the mono- and diamide functionalized derivatives of EDT-TTF with the double charged nitroprusside anion [ FeNO(CN) 5] 2- (NP): $\kappa $ -(BDH-TTP) 4[NP]C 6H 5NO 2 (1), $\kappa $ -(BDH-TTP) 4[NP] (2), (BDH-TTP) 2[NP] (3), $\alpha $-[ EDT-TTF-CONH 2] 4[NP] (4), $\beta $ -[ EDT-TTF-(CONH 2)2] 2[NP] 0.5(C 6H 5NO 2)0.5 (5) have been synthesized. The crystal structures and transport properties of 1 - 5, as well as electronic band structures of 1and 2 have been studied. Key words. organic conductors based on radical cation salts - X-ray and band structure - conductivity.



© EDP Sciences 2004