Issue
J. Phys. IV France
Volume 07, Number C1, Mars 1997
7th INTERNATIONAL CONFERENCE ON FERRITES
Page(s) C1-361 - C1-362
DOI https://doi.org/10.1051/jp4:19971147
7th INTERNATIONAL CONFERENCE ON FERRITES

J. Phys. IV France 07 (1997) C1-361-C1-362

DOI: 10.1051/jp4:19971147

Magnetic Properties of Nonstoichiometric Perovskites R1-xMnO3+y (R = La, Eu)

A.V. Zubetz, I.O. Troyanchuk and E.F. Shapovalova

Institute of Physics of Solids and Semiconductors, Academy of Sciences of Belarus, P. Brovki 17, Minsk 22072, Belarus


Abstract
The crystal structure and magnetic properties of orthomanganites R1-xMnO3+y (R=La, Eu ; x≤0.2 ; y ≤0.13) were investigated. It was shown that the increase of oxygen content leads to the transformation from the antiferromagnetic to the ferromagnetic state in these compounds. The Curie temperatures of La1-xMnO3+y and freezing temperatures of magnetic clusters for Eu1-xMnO3+y in the samples with deficit of A-cations are higher than those in parent compounds (with x=0). The magnetic data indicate that the mixed magnetic state involving ferro- and antiferromagnetic domains is realized in the intermediate range of x, y values.



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