| Numéro |
J. Phys. IV France
Volume 114, April 2004
|
|
|---|---|---|
| Page(s) | 611 - 615 | |
| DOI | https://doi.org/10.1051/jp4:2004114145 | |
J. Phys. IV France 114 (2004) 611
DOI: 10.1051/jp4:2004114145
2-Cyano-4,4,5,5-tetramethyl-4,5-dihydro-1 H-imidazol-1-oxyl-3-oxide as key compound for preparation of nitronyl and imino nitroxides
E.V. Tretyakov, G.V. Romanenko and V.I. OvcharenkoInternational Tomography Center, Siberian Branch, Russian Academy of Sciences, Institutskaya Str., 3a, 630090 Novosibirsk, Russia
Abstract
A series of nitronyl and imino nitroxides: amides
2, 13 (NN-C(O)-NH
2, INC(O)NH
2),
iminoethers 3a,b, 15 (NN-C(NH)-OR (R = CH
3,
2-Pr), IN-C(NH)-OCH
3), carboxylates 4, 14a-c
(NN-C(O)-OK, IN-C(O)-OX (X = K
+, (
n-Bu)
4N
+)), and paramagnetic
tetrazoles 5, 7-12 were synthesized from
2-cyano-4,4,5,5-tetramethyl-4,5-dihydro-1
H-imidazole-1-oxyl-3-oxide
(NN-C
N). The crystal and molecular structure was determined for all
compounds except 4, 14c, and 15.
Key words. Nitronyl nitroxide - imino nitroxide - structure -
magnetic properties - molecular materials.
© EDP Sciences 2004