J. Phys. IV France 123 (2005) 213-218
Characterization of active sites on W2-xMox(PO4)2 ( ) in butan-2-ol conversionM. Kacimi1, S. Gharbage1, F. Bozon-Verduraz2 and M. Ziyad2
1 Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie, Rabat, Maroc
2 Groupe de Chimie des Matériaux Divisés et Catalyse, ITODYS, UMR-CNRS 7086, Université Paris 7-Denis Diderot, 2 place Jussieu, 75251 Paris, France
The molybdenum-tungsten phosphate (W MoO3(PO 4)2) was synthetised and characterised using several techniques. Its catalytic performances was studied in butan-2-ol conversion. The UV-visible investigations showed that the catalyst contains Mo(V) ions. This results was confirmed by the EPR spectra. Additional U.V. visible in-situ experimentss, in dynamic conditions revealed that butan-2-ol reduces Mo(VI) into Mo(V) ions. The active sites in the catalytic reaction appearto be built up arround the Mo(VI) ions.
© EDP Sciences 2005