| Numéro |
J. Phys. IV France
Volume 114, April 2004
|
|
|---|---|---|
| Page(s) | 683 - 688 | |
| DOI | https://doi.org/10.1051/jp4:2004114164 | |
J. Phys. IV France 114 (2004) 683
DOI: 10.1051/jp4:2004114164
Syntheses, characterization and crystal structures of a new functionalised TTF derivative and its Ni(II) complex
S. Dolder1, S.-X. Liu1, G. Labat2 and S. Decurtins11 Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, 3012 Bern, Switzerland
e-mail: silvio.decurtins@iac.unibe.ch
2 Institut de Chimie, Université de Neuchâtel, Avenue Bellevaux 51, 2007 Neuchâtel, Switzerland
Abstract
The new ligand 4,5-bis (2-pyridylmethylsulfanyl)-4',5'-bis(cyanoethylthio)tetrathiafulvalene
(BPM-BCET-TTF) and its nickel(II) complex have been prepared and crystallographically
characterized. The Ni(II) complex shows octahedral geometry around the metal ion with the
coordination site occupied by the pyridyl nitrogen atoms, the thioether sulfur atoms of the
ligand and cis coordination of the halide ions.
Key words. Nickel (II) complex;
4,5-bis(2-pyridylmethylsulfanyl)-4',5'-bis(cyanoethylthio) tetrathiafulvalene
© EDP Sciences 2004