J. Phys. IV France 114 (2004) 591
Humidity sensitive conductivity of (BEDO-TTF) Br(H O) as a bulk propertyH. Yamochi1, 1, T. Haneda1, A. Tracz2, J. Ulanski3, O. Drozdova4, K. Yakushi4 and G. Saito1
1 Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan
2 Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, ul. Sienkiewicza 112, 90-363 Lódz, Poland
3 Department of Molecular Physics, Faculty of Chemistry, Technical University of Lódz, 90-924 Lódz, Poland
4 Institute for Molecular Science, Okazaki 444-8585, Japan
The title complex shows the reversible loss and regain of water of crystallization associated with the modulation of the conductivity. The origin of higher resistivity in the dry atmosphere is regarded as the disorder in the crystals. Key words. BEDO-TTF - , crystal structure, - RDP film, - organic metal.
© EDP Sciences 2004