| Numéro |
J. Phys. IV France
Volume 114, April 2004
|
|
|---|---|---|
| Page(s) | 589 - 590 | |
| DOI | https://doi.org/10.1051/jp4:2004114140 | |
J. Phys. IV France 114 (2004) 589
DOI: 10.1051/jp4:2004114140
New organic conductor (DMET) 2CuCl 2: Synthesis, structure and physical properties
M. Umemiya1, K. Goto1, S. Takaishi1, H. Miyasaka1, K.-I. Sugiura1, M. Yamashita1, H. Nishikawa1, K. Kikuchi1, I. Ikemoto1, Y. Yokochi2, H. Ito2 and S. Kuroda21 Department of Chemistry, Tokyo Metropolitan University & CREST, 1-1 Minami-ohsawa, Hachioji 192-0397, Japan
2 Department of Applied Physics, Nagoya University, Nagoya 464-8603, Japan
Abstract
A new organic conducting salt, (DMET)
2CuCl
2, was prepared by a diffusion method, crystal and electrical structures of
which were investigated. The single-crystal X-ray crystallography revealed
that DMET molecules are alternately stacked to form quasi-one-dimensional
(Q-1D) columns. This salt exhibited a metallic behavior with lowering
temperature (
S
cm
-1), where
several resistance jumps were observed.
Key words. Organic conductor - Diffusion method - Crystal
structure - Quasi-one-dimensional - (DMET)
2CuCl
2..
© EDP Sciences 2004