Accès gratuit
Numéro
J. Phys. IV France
Volume 113, January 2004
Page(s) 7 - 9
DOI https://doi.org/10.1051/jp4:20040002


J. Phys. IV France
113 (2004) 7
DOI: 10.1051/jp4:20040002

Solid-liquid phase equilibria for aromatic compounds

M. Benkhennouf, K. Kamel and A. Dahmani

Laboratoire de Thermodynamique et Modélisation Moléculaire, Faculté de Chimie, USTHB, BP. 32 El-Alia, 16111 Bab-Ezzouar, Alger, Algérie


Abstract
A Differential Scanning Calorimetry (DSC 7, Perkin-Elmer) is used to determine the solid- liquid phase diagram for polycyclic aromatic compounds of biphenyl and 2,3-dimethylnaphthalene. The eutectic temperature is also measured. In this work, the experimental diagram cmpared satisfactorily with group contribution models, Modified UNIFAC (Lyngby and Dortmund versions).



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