MOBILITY OF EXCESS ELECTRONS IN ACETONITRILE VAPOUR AND MULTIPLE SCATTERING PROCESSES IN DENSE POLAR VAPOURS

P. KREBS; St. VAUTRIN

doi:doi:10.1051/jp4:1991514

Numéro		J. Phys. IV France Volume 01, Numéro C5, Décembre 1991 COLLOQUE WEYL VII International Conference on METALS IN SOLUTION


Page(s)		C5-115 - C5-120
DOI		https://doi.org/10.1051/jp4:1991514

COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION

J. Phys. IV France 01 (1991) C5-115-C5-120
DOI: 10.1051/jp4:1991514

MOBILITY OF EXCESS ELECTRONS IN ACETONITRILE VAPOUR AND MULTIPLE SCATTERING PROCESSES IN DENSE POLAR VAPOURS

P. KREBS and St. VAUTRIN

Institut für Physikalische Chemie und Elektrochemie der Universität Karlsruhe, Kaiserstrasse 12, D-75 Karlsruhe, Germany

Abstract
Electron mobilities in acetonitrile vapour are reported for the temperature range 298 [MATH] T [MATH] 398 K up to vapour densities of about 7 x 10¹⁹ cm^-3 which show very strong deviations from the Lorentz behaviour. These results and those of electrons in other polar gases can be partially explained by density corrections of quantum character proposed by Polischuk.