| Numéro |
J. Phys. IV France
Volume 01, Numéro C5, Décembre 1991
COLLOQUE WEYL VIIInternational Conference on METALS IN SOLUTION |
|
|---|---|---|
| Page(s) | C5-61 - C5-70 | |
| DOI | https://doi.org/10.1051/jp4:1991507 | |
COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION
J. Phys. IV France 01 (1991) C5-61-C5-70
DOI: 10.1051/jp4:1991507
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
© EDP Sciences 1991
International Conference on METALS IN SOLUTION
J. Phys. IV France 01 (1991) C5-61-C5-70
DOI: 10.1051/jp4:1991507
PHYSICAL PROPERTIES OF ALKALI METAL-AMMONIA (AMINE) SOLUTIONS STUDIED BY MAGNETIC RESONANCE METHODS
Y. NAKAMURADepartment of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan
Abstract
Characteristic features of the physical properties of metal-ammonia(amine) solutions are reviewed. The concentration fluctuations and the pairing of the excess electrons are considerable in the intermediate region of Li- and Na-ammonia solutions, where metal-nonmetal transition takes place. On the other hand, Li-methylamine solutions seem more homogeneous in the intermediate region, exhibiting similar electric properties to those of molten semiconductors.
© EDP Sciences 1991