EDP Sciences Journals List
  • French
  • English
Advanced Search
Subscriber Authentication Point
Free access article

Issue J. Phys. IV France
Volume 11, Number PR10, Décembre 2001
Journées d'Étude des Équilibres entre Phases
Page(s) Pr10-197 - Pr10-199
DOI http://dx.doi.org/10.1051/jp4:20011030

Journées d'Étude des Équilibres entre Phases

J. Phys. IV France 11 (2001) Pr10-197-Pr10-199
DOI: 10.1051/jp4:20011030

Représentation topologique (p, T) du trimorphisme du ferrocène : métastabilité intrinsèque de la phase triclinique

S. Toscani1, P. De oliveira2 and R. Céolin1

1  Laboratoire de Chimie Physique, Faculté de Pharmacie, 4 avenue de l'Observatoire, 75006 Paris, France
2  Laboratoire de Biophysique, Muséum National d'Histoire Naturelle, 43 rue Cuvier, 75005 Paris, France


Abstract
Structural and thermodynamic data reported in literature about the three crystalline phases of ferrocene are used to build up a topological representation of its (p,T) phase diagram. Two phases (orthorhombic and monoclinic) exhibit stable phase regions whose temperature ranges increase with increasing pressure. The triclinic phase is found to be metastable whichever temperature and pressure. In the (p,T) diagram, it is not associated with any state of lowest energy although it transforms into the monoclinic phase according to a transition which is reversible. It is shown that this occurs in the phase region where the orthorhombic phase is the stable phase.



© EDP Sciences 2001


What is OpenURL?

The OpenURL standard is a protocol for transmission of metadata describing the resource that you wish to access. An OpenURL link contains article metadata and directs it to the OpenURL server of your choice. The OpenURL server can provide access to the resource and also offer complementary services (specific search engine, export of references...). The OpenURL link can be generated by different means.
  • If your librarian has set up your subscription with an OpenURL resolver, OpenURL links appear automatically on the abstract pages.
  • You can define your own OpenURL resolver with your EDPS Account. In this case your choice will be given priority over that of your library.
  • You can use an add-on for your browser (Firefox or I.E.) to display OpenURL links on a page (see http://www.openly.com/openurlref/). You should disable this module if you wish to use the OpenURL server that you or your library have defined.