J. Phys. IV France 7 (1997) C2-257-C2-258
XANES Study of the Charge Transfer upon Lithium Intercalation into Lamellar Transition Metal DichalcogenidesZ.Y. Wu, S. Lemaux, P. Moreau, P. Gressier, F. Lemoigno and G. Ouvrard
Institut des Matériaux de Nantes, UMR 110, CNRS-Université de Nantes, 2 rue de la Houssinière, 44072 Nantes cedex 03, France
XANES S K- and ELNES Ti L2,3-edges of TiS2 and LiTiS2 are studied by means of multiple scattering simulations and band structure calculations. Semi-metallic nature of TiS2 is clarified as well as the important role of sulfur, which was before this work believed to be a spectator in the intercalation process.
© EDP Sciences 1997