Numéro
J. Phys. IV France
Volume 04, Numéro C4, Avril 1994
3rd International Conference Laser M2P
Page(s) C4-767 - C4-770
DOI http://dx.doi.org/10.1051/jp4:19944210
3rd International Conference Laser M2P

J. Phys. IV France 04 (1994) C4-767-C4-770

DOI: 10.1051/jp4:19944210

Laser-induced fluorescence spectra of the non symmetrical isotopomers of CuCl2

A.J. BOUVIER, E. BOSCH and J.C. COSTE

Laboratoire de Spectrométrie Ionique et Moléculaire, URA 171 du CNRS, Université Lyon I, Bât. 205, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne cedex, France


Abstract
Investigations of the ground state of CuCl2 have been pursued recording laser induced fluorescence spectra on a BOMEM DA3 Fourier transform spectrometer in the range 10000-16500 cm-1. In this work, we specially extend the study to the non symmetrical isotopomers 35Cl63Cu37Cl and 35Cl65Cu37Cl. Band-by-band and polynomial fits allowed us to determine rotational and vibrational constants in the range v''1=0-9. v''=0-6 that will be compared to the constants of the main symmetrical isotopomers 63Cu35Cl2. An approximate Valence Force Field model is tested and discussed.



© EDP Sciences 1994