Numéro
J. Phys. IV France
Volume 01, Numéro C7, Décembre 1991
2nd International Conference
Laser M2P
Page(s) C7-485 - C7-488
DOI http://dx.doi.org/10.1051/jp4:19917128
2nd International Conference
Laser M2P

J. Phys. IV France 01 (1991) C7-485-C7-488

DOI: 10.1051/jp4:19917128

INTRACAVITY LASER SPECTROSCOPY OF ELEMENTARY PROCESSES BASED ON A CW RING DYE LASER

M.G. BRYUKOV1, A.A. KACHANOV2, S.I. PANOV1 and O.M. SARKISOV1

1  Institute of Chemical Physics Acad. Sci. USSR, Kosygina 4, Moscow 117334, USSR
2  Institute of Spectroscopy Acad. Sci. USSR, Moscow Reg., Troitsk 142092, USSR


Abstract
An improved version of an intracavity laser spectrometer based on a ring travelling wave dye laser is demonstrated, a rate constant measurement of the HNO + O2 reaction being used as an example. This spectrometer previously shown to have quantum noise limited sensitivity in absorption measurements permits studying slow chemical reactions at very low concentrations of active particles. Efficient algorithm of calculation concentrations of molecules in chemical reaction cell is also developed.



© EDP Sciences 1991