Numéro
J. Phys. IV France
Volume 01, Numéro C7, Décembre 1991
2nd International Conference
Laser M2P
Page(s) C7-443 - C7-446
DOI http://dx.doi.org/10.1051/jp4:19917118
2nd International Conference
Laser M2P

J. Phys. IV France 01 (1991) C7-443-C7-446

DOI: 10.1051/jp4:19917118

MULTI-DIMENSIONAL ELECTRONIC AND NUCLEAR COORDINATES INFLUENCING LASING ACTION

C.K. JØRGENSEN

Section de Chimie, Université de Genève, 30 Quai Ansermet, CH-1211 Genève 4, Switzerland


Abstract
The easy, and some far more counterintuitive, parts of quantum mechanics are analyzed for monatomic ions ; for the time independent Schrödinger solution for a given set of N nuclei and a number of electrons ; and if the Born-Oppenheimer factorization is acceptable, the (3N-5) dimensional potential surfaces of each electronic state are significant for Stokes shifts of asymmetric luminescence bands, and unexpected shape and positions of new absorption bands due to laser-induced quasi-stationary small concentrations of a low-symmetry excited state.



© EDP Sciences 1991