Numéro
J. Phys. IV France
Volume 01, Numéro C5, Décembre 1991
COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION
Page(s) C5-217 - C5-222
DOI http://dx.doi.org/10.1051/jp4:1991525
COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION

J. Phys. IV France 01 (1991) C5-217-C5-222

DOI: 10.1051/jp4:1991525

THE PREPARATION OF METALLA-SULPHUR/SELENIUM COMPLEXES FROM REACTIONS IN LIQUID AMMONIA

J.D. WOOLLINS

Department of Chemistry, Imperia1 College London, GB-London SW7 2AY, Great-Brirain


Abstract
The preparation of metalla-sulphur-nitrogen and metalla-selenium-nitrogen complexes from reactions in liquid ammonia is described. For example, reaction of PtCl2(PR3)2 with [S4N3]Cl in liquid ammonia yields Pt(S2N2)(PR3)2. Similar reactions with SOCl2 SO2Cl2 and SeCl4 give complexes containing NSO-, [SO2(NH)2]2- and Se2N22- ligands respectively.



© EDP Sciences 1991