Numéro
J. Phys. IV France
Volume 01, Numéro C5, Décembre 1991
COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION
Page(s) C5-61 - C5-70
DOI http://dx.doi.org/10.1051/jp4:1991507
COLLOQUE WEYL VII
International Conference on METALS IN SOLUTION

J. Phys. IV France 01 (1991) C5-61-C5-70

DOI: 10.1051/jp4:1991507

PHYSICAL PROPERTIES OF ALKALI METAL-AMMONIA (AMINE) SOLUTIONS STUDIED BY MAGNETIC RESONANCE METHODS

Y. NAKAMURA

Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan


Abstract
Characteristic features of the physical properties of metal-ammonia(amine) solutions are reviewed. The concentration fluctuations and the pairing of the excess electrons are considerable in the intermediate region of Li- and Na-ammonia solutions, where metal-nonmetal transition takes place. On the other hand, Li-methylamine solutions seem more homogeneous in the intermediate region, exhibiting similar electric properties to those of molten semiconductors.



© EDP Sciences 1991